Partitioning of elements between peridotite and H₂O at 2.0–3.0 GPa and 900–1100°C, and application to models of subduction zone processes     

John C. Ayers  Sondra K. Dittmer  Graham D. Layne 《Earth and Planetary Science Letters》1997,150(3-4):381-398

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泌阳凹陷核桃园组微量元素演化特征及其古气候意义   总被引：31，自引：6，他引：31  

王随继  黄杏珍 《沉积学报》1997,15(1):65-70

泌阳凹陷下第三系核桃园组总体上表现为一个大的湖退体系，而其中的微量元素含量及有关元素比值却呈现出细微而明显的旋回变化特征。本文依据泥岩、页岩和碳酸盐岩中Ｔｉ、Ｓｒ、Ｂａ等十六种微量元素含量及Ｓｒ/Ｂａ、Ｆｅ/Ｍｎ、Ｓｒ/Ｃｕ等七种比值的变化特征，结合古盐度及岩相资料，对核桃园组沉积时的古气候作了系统的研究，基本上分出了温暖潮湿、干湿交替、炎热干旱、温热半干旱四类较为特征的古气候类型，以期为油气勘探提供依据。  相似文献   

催化褪色光度法测定痕量锰的研究及应用   总被引：2，自引：0，他引：2  

康文  周发连 《华东地质学院学报》1997,20(2):141-146

本研究了在ＰＨ＝４．０醋酸－醋酸钠缓冲溶液中，锰催化ＫＩＯ４氧化５－Ｂｒ－ＰＡＤＡＰ的褪色反应及其动力学条件，建立了一个痕量锰的高灵敏度新方法，方法灵敏度为１．３２×１０＾－１０ｇ／ｍｌ，测定范围Ｍｎ＾２＋浓度为０￣１．５μｇ／ｍｌ，用于测定人发，自来水，茶叶中痕量锰，结果满意。  相似文献   

长春市城市土壤中重金属元素的积累及其微生物特性研究   总被引：10，自引：2，他引：10  

刘乃瑜  马小凡  谢忠雷  郭平 《吉林大学学报(地球科学版)》2004,(Z1)

由于人为活动的影响,长春市城市土壤中重金属Cu、Zn、Pb、Cd已有了显著积累。在重金属的胁迫下,土壤微生物特征发生了明显变化,微生物代谢活动明显增强,但微生物生物量却有较大的降低。微生物生理生态参数土壤微生物量碳与总有机碳的比值(Cmic/Corg)和代谢商QCO2(微生物呼吸作用强度与微生物量碳的比值)变化异常。研究表明,微生物特性可作为城市土壤环境中重金属含量变异的有效指标。  相似文献   

磁学方法在环境污染研究中的应用   总被引：12，自引：0，他引：12  

闫海涛  胡守云  朱育新 《地球科学进展》2004,19(2):230-236

环境磁学方法问世20多年来，因其快速、灵敏、经济、无破坏性和信息量大的特点，在环境研究中得到广泛的应用。磁学方法可用于传统的污染分析技术（化学）之前的预研究，而后者一般耗费大量人力、物力和时间；它也可以作为环境污染评估的代用指标。近年来，随着世界环境污染问题的日益严重和倍受关注，磁学方法被广泛地应用于环境污染研究。欧洲环境磁学专家在重建污染历史、监测现代环境污染、追踪与分离污染源等方面，开展了大量的工作，并积累了一定的经验。介绍了磁学方法用于污染研究的显著特点、主要用途、野外工作方法以及相关仪器；展示了在大气、土壤、潮滩、河流、湖泊以及海洋等不同环境系统中，利用磁手段研究污染的成果和最新进展；对 于一些难点、热点问题，如磁性机理的研究、多源污染的分离、强烈多变的人类活动对获取有意义磁讯号的影响等，做了相应的分析和总结。  相似文献   

安徽铜陵矿集区海底喷流沉积体系的流体包裹体微量元素对比   总被引：7，自引：3，他引：7  

徐九华  谢玉玲  杨竹森  蒙义峰  曾普胜 《矿床地质》2004,23(3):344-352

铜陵矿集区与铜-金(多金属)矿床有关的热液活动主要有两大体系。即与海西期海底喷流沉积有关的热液体系和与矽卡岩矿化有关的燕山期岩浆热液体系。查明这两类热液体系的流体包裹体特征对区域找矿和矿床成因研究都有实际意义。在包裹体岩相学研究基础上，应用ICP-MS技术和热爆提取方法，研究了新桥、冬瓜山、峙门口、铜官山、朝山等矿床具代表性的热液石英中流体包裹体的微量元素、稀土元素特征。结果表明，两类热液体系在流体包裹体特征上有较大的区别，在流体的微量元素和稀土元素特征方面也很不相同。海底喷流沉积体系的热液石英中流体包裹体与岩浆热液体系的相比。稀土总量较高，LREE／HREE比值较大，δEu不明显。且Mo／(W Sn)比值较高，反映流体中成矿物质的深源特征；Ga／T1、Rb／Cs大。Zr／Hf低，也不同于岩浆热液体系。  相似文献   

云南会泽超大型铅锌矿床成因研究中的几个问题   总被引：6，自引：0，他引：6  

黄智龙  李文博  张振亮  韩润生  陈进 《矿物学报》2004,24(2):105-111

位于川-滇-黔铅锌多金属成矿域中南部云南会泽超大型铅锌矿床可能是一种新的铅锌矿床类型，该类铅锌矿床明显特征是规模大、品位富、伴生有用元素多，暗示其成矿环境较为特殊。从成矿时代、成矿物质来源、成矿流体来源与演化，以及峨眉山玄武岩与成矿的关系等方面分析了会泽超大型铅锌矿床的研究进展及国内外研究现状，认为矿床成矿时代与西南大面积峨眉山玄武岩成矿时代相近，成矿物质和成矿流体具有“多源性”，成矿流体存在均一化过程，区域大规模流体运移在该区铅锌成矿过程中具有重要意义，峨眉山玄武岩岩浆活动与铅锌成矿具有密切的成因联系，矿床可能为“均一化成矿流体贯入成矿”的产物。  相似文献   

豫西济源谭庄组河流沉积中的Stipsellus遗迹组构   总被引：4，自引：0，他引：4  

胡斌  张国成  郭卫星  齐永安  张利伟 《煤田地质与勘探》2004,32(3):1-5

豫西济源盆地上三叠统谭庄组下段为曲流河沉积。本文通过描述和分析谭庄组河流沉积特征，划分了4种不同河流沉积组合类型，识别出Stipsellus遗迹组构，并发现该遗迹组构常与曲流河沉积物伴生，可作为此类沉积的典型生物遗迹标志。其中，Stipsellus sp．A代表发育在河漫滩较浅水体下或潮湿的软底细粒沉积物中的一种遗迹组构类型；Stipsellus sp．B则代表发育在曲流砂坝上部的男一种遗迹组构类型。  相似文献   

Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry   总被引：190，自引：0，他引：190  

Honglin Yuan  Shan Gao  Xiaoming Liu  Huiming Li  Detlef Günther  Fuyuan Wu 《Geostandards and Geoanalytical Research》2004,28(3):353-370

Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and ²⁹Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given.  相似文献   

Genesis and evolution of the lithospheric mantle beneath the Buffalo Head Terrane, Alberta (Canada)   总被引：2，自引：0，他引：2  

S. Aulbach  W.L. Griffin  S.Y. O''Reilly  Tom E. McCandless 《Lithos》2004,77(1-4):413-451

Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m². The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.

A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.

Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic ¹⁸⁷Os/¹⁸⁸Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.

A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.

If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events.  相似文献